ࡱ> LNK bjbjΚΚ y6G$P( < L' 4 ' ' ' ' ' ' ',)C,8' 8'! M'!!!   '! '!!r#&hcHJ!&&c'0'&,!,&!& 8'8'! ',  z:   * INTERPRETATION - "Department" means College/School/Department/Centre/Unit as relevant. 18.38.1 HAZARDS Refrigeration units may represent a hazard for a variety of reasons. Improper use of laboratory units for food storage for general consumption by staff/students is an on-going problem where such units are also used for storing toxic chemicals or pathogenic biological agents. The confined and well-sealed space permits vapours from improperly sealed containers to accumulate. These vapours may be toxic and users may breathe in fumes that may exceed safe levels. Flammable vapours may also accumulate if flammable liquids are stored for the same reason and may be ignited by sparks or heat sources. (Evenly tightly capped containers can allow flammable vapour to evaporate). The results of the latter could be explosion, fire or life threatening. Walk in refrigerators may result in persons being trapped within and dying from hypothermia if locks are permitted on the outside and emergency buttons to over-ride the door catch are not provided within. 18.38.2 RISKS The risks associated with the aforementioned hazards are to be assessed by the Department (using the appropriate technical input where necessary). These assessments shall be carried out using: Check lists provided (where applicable) and Departmental Hazard Identification/Risk Assessment Work Sheets contained in Document No.3 i.e. Departmental Hazard Risk Assessment (D.H.R.A.). 18.38.3 ARRANGEMENTS AND CONTROLS REQUIRED These hazards and risks will be minimised by the following arrangements and controls: Careful training for personnel using and storing chemicals in fridges should be part of the safety programme. (Particular attention must be given on how to seal containers placed in refrigerated units). Ensure that refrigerators intended for storing flammable liquids are equipped with flammable vapour proof controls. The light switch, the light itself, thermostat, the defrost heater and its control, the compressor and fan must be intrinsically safe for flammable vapours. Ensure refrigerators have magnetic door catches instead of mechanical latch to eliminate sources of sparks. The door shall have locks to prevent unauthorised access to materials that are hazardous. Great care shall be exercised when storing materials that have flash points well below temperatures found in most fridges and some freezers whose flammable limit concentrations (volume % in air) span a wide range. For example, Carbon disulphide, Diethylether, Ethylene oxide, Ethylnitrite, Propylene oxide and Vinyl ethyl ether. Most of these evaporate rapidly so they quickly reach equilibrium concentrations in the confined space. Explosion-proof refrigerators must be used if it has to operate in hazardous atmospheres. These units are designed to remove all internal and external sources of ignition. Ensure "frost-free" i.e. anti-defrost models do not allow vapour to drain to the compressor and are explosion proof, if flammable liquids are stored. Walk-in fridges shall have a door lock over-ride push button device within (adjacent to the door). Other locks e.g. bar and padlocks shall be prohibited. Beakers, flasks, bottles covered with aluminium foil or plastic wrap shall not be allowed for storage with volatile substances. Corks or glass stoppers should not be used for sealing preferably use screw-cap tops with interior seal. Domestic refrigerators should not be modified for laboratory use where flammable storage is required. Warning signs shall be placed on doors indicating whether or not refrigerators are suitable for flammable liquids. Containers in fridges shall be clearly labelled and firmly fixed with the following information: name of substance nature of hazard owner's name date it was stored date when it may be disposed of 18.38.3 ARRANGEMENTS AND CONTROLS REQUIRED (Cont.) The door of the unit should also display information about any toxic or hazardous materials stored in the refrigerator In the case of substance that may become reactive at room temperature, precautions must be taken against electrical supply interruptions. Special precautions must be taken when animals, sacrificed by ether anaesthesia, are stored in refrigerators. This extremely volatile solvent will quickly vaporise from animal tissues and reach its lower flammable limit creating a potential explosive hazard. 18.38.4 ARRANGEMENTS AND CONTROLS The details of the Arrangements and Controls in place and those required in the short, medium and long term, shall be set out by the Department in the forms provided in Document No.4 i.e. Departmental Safety Action Plan (D.S.A.P.). These Arrangements and Controls shall be reviewed and updated on a yearly basis. 18.38.5 RESPONSIBILITIES The following personnel are responsible in the Department/Lab/Area for ensuring the implementation and ongoing compliance with the aforementioned arrangements and controls. AREA/LOCATIONPERSON RESPONSIBLE1.2.3.4.5.6.   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