深夜亚洲福利久久

12.2 Polyatomic molecules: principle of equipartition of energy

The Physlet on the can be used understand the basic ideas underlying the principle of equipartition of energy in a gas.

First choose a small number (say 20) of molecules of a monatomic gas and run the simulation; as one would expect, the total energy of the system remains constant.

Next try the same number of diatomic molecules. In this case the total energy is also constant but is distributed between translational and rotational forms. Because of the small number of molecules involved there is a statisical fluctuation in the energy in each of these modes but on average half the energy goes into each mode. Using a larger number of molecules, the statistical fluctuations are reduced.

Finally, investigate the situation in which the system is comprised of a mixture of monotomic and diatomic molecules.

漏2013 W. Christian and M. Belloni. Creative Commons LicenseReleased under a Creative Commons Attribution-NonCommercial-NoDerivs License (Physlets were developed at Davidson College and have been converted from Java to JavaScript)

Some polyatomic molecules:
          

Understanding Physics

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Mansfield and O'Sullivan, Understanding Physics, 3rd ed., John Wiley & Sons, Chichester (2020),

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